My first rec would be get a solid board for your system. The Biostar with non solid state caps is gonna ut your entire build as a reliabilty risk. I recommend a ASUS or Gigabyte board with all solid state caps. Also I'm hard pressed on a gigabyte mobo atm as I had one in my current PC and it eventually got hit with the power-cycling problem, and despite GB's crappy CS after I got it back from repairs (they said corrupted bios) it did not fair any better. And looking at the current ones out now people still complain of this happening to them down the line.
I was thinking about a ASRock with solid gold caps:
http://www.newegg.com/Product/Produc...82E16813157263
Looking at ASUS boards this one got good reviews (both on newegg and off) has solid caps even though it's not mentioned on newegg:
http://www.newegg.com/Product/Produc...82E16813131790
Seems neater then the ASRock and as cool as the dual nics is I'm not going to have any use for it.
If you are gonna run a GTX580 you will want a larger powersupply. If you are doing the DIY kit 4 then you are likely going to be mounting 9 fans on the external rad and drawing this combined with a pump, HDD and a monster vid card I am seeing a 1000 watt for your setup. It is also important to no overload your rails I am running al of the fans on their own rail to avoid messing up my PSU. I ran the pump and lighting on a seperate rail as well.
The system i built I did not put silicon around my heatsink and proc. This is not a required step and you get no benefit by doing this.
I havent recorded temps yet but my setup is different from your so I thier will be a variance especially on the GPU I have built a few systems with 580's and upgraded cooling is a must so oil will help you out alot.
no leaking or seeping on my system. with the way this setup is built you will not have any seeping down cables with the way the tray and IO are made. The biggest issue with previous cable seeping was because the power supply was not able to mounted on to the io tray in previous versions since they used a smaller tank. This made them have to submerge the power supply on the bottom of the case so oil would seep along the psu cable. With V4 the psu mounts on the IO tray so this issue has been resolved this is possible because of the larger tank.
The hardrive pass thru is sill molex but if you are good with wiring you can take a sata pig tail from your modular powersupply and cho it to make it connect with a molex end to that plug works great and with a little heatshrink it looks factory.
The fittings that come with this system are compression fittings not true quick disconnect fittings. They are designed to make the construction and desconstruction of the system easier. A real quick disconnect will stop and hold the fluids in the lines once disconnected these will not do that and are wide open allowing for great flow. I couldnt believe how well that swiftech pump pushed the oil so easily. THis oil systems has roughly the same flow as my liquid rig.